A road kill deer sure would come in handy

I read somewhere that some guys actually tested small caliber air rifles on a road killed deer to see if you could effectively brain one with a .177 or .22 airgun. They concluded that it is possible with proper shot placement, but definitely didnt recommend it. Of course, it looks like my airgun will be a smoothbore, so a boiler room shot is the only way to go.
Actually, I bought the parts today to build a different valve that will allow me to use interchangeable barrels and air chambers. The parts only cost $7 and should easily outperform a sprinkler valve. Not to mention, it will handle 3 to 4 times the pressure.

Using a .72 roundball, GGDT predicts this design will produce nearly 200 fpe. It will also have a thornily stopping power of 80, so it should be more than adequate to put a deer down (recommended is a 50 on whitetail). I'm thinking that it will produce a massive wound channel, be capable of crushing ribs, and damaging the lungs and heart enough to provide a clean kill for an airgun. Much better than the .54 I was thinking of last night. Here is an article from a guy who has done a lot of airgun hunting:
http://www.americanairgunhunter.com/deertracks.html. It is this article that suggests to me the effectiveness of a larger caliber as opposed to the .45 to .50 range they are using. He's got a video of the hunt on his site too!
My goal is to take a small doe within 25 yards. All of my homemade airguns can shoot at least a 2" to 3" group at that range with a unsupported pvc barrel. The copper barrel I plan to use will be far more rigid and should be able to shoot even tighter. The last deer I shot was only 10 paces from me, I stalked him on foot and brought him down with a 30-30.

As a precaution, I'll have my SKS in case I need any followup shots, or bring my buddy with his AR15. A buddy would be nice to do some filming as well...